The interior angle and exterior angle are supplementary so they add up to 180 degrees
So, if the ratio is 2:3 then the angles can be shown as
2x+3x=180
5x=180
x=36
so the interior angle is 2(36)=72 and the exterior angle is 3(36)=108
Wait, something is wrong here... there are no regular polygons with all the interior angles each measuring 72 degrees.
regular triangle= 60 degrees each
regular quadrilateral(square)= 90 degrees each
regular pentagon= 108 degrees each
My guess is the the ratio is turned around and supposed to say either: "the ratio of interior to exterior angle in a reg. polygon is 3:2" or "the ratio of exterior to interior angle in a reg. polygon is 2:3".
In either case, the polygon would be a pentagon with exterior angles each measuring 72 degrees.